Heating a substance — the heating curve
By the end of this topic you'll know what happens to temperature when you heat a substance steadily, and why it stops rising while the substance is melting or boiling.
Part 1Heat it steadily and watch the temperature
Take some ice straight from the freezer and heat it gently and steadily — say, with a Bunsen burner turned to a constant flame. If you measure the temperature every minute, you might expect it to climb in a straight line all the way up. It doesn't.
At first the temperature rises. Then, while the ice is melting into water, the temperature stops climbing and stays flat for a while — even though you're still heating it. Once it's all melted, the temperature rises again. Then, while the water is boiling into steam, it goes flat again.
Those flat bits are called plateaus. A graph of temperature against time, with these two flat sections, is a heating curve.
Keywords for Part 1
- Heating curve
- A graph of temperature against time as a substance is heated steadily.
- Plateau
- A flat part of the graph where the temperature stays the same even though heating continues.
- Melting point / boiling point
- The temperatures at which a substance melts (solid → liquid) and boils (liquid → gas). For pure water these are 0 °C and 100 °C.
Part 2Why does the temperature go flat?
This is where the particle model explains everything. Temperature is a measure of how fast the particles are moving — how much kinetic energy they have. When you heat a solid, you're feeding energy in, the particles vibrate faster, and the temperature climbs.
But to melt, the particles need to break free from their fixed positions. That takes energy — and while the substance is melting, all the energy you put in goes into breaking those bonds between particles, not into making them move faster. So the temperature doesn't change. The same thing happens at the boiling plateau: the energy goes into pulling the particles right apart into a gas.
In short: during a change of state, the energy goes into changing state, not raising temperature. Once the change of state is finished, the temperature starts rising again.
⚠ Watch out — "you've stopped heating it"
A flat plateau does not mean you've turned the heat off. You're still heating the substance the whole time. The temperature stays the same because the energy is being used to change the state (break the particles apart), not to make the particles move faster. The thermometer only measures particle speed, so it sits still until the change of state is complete.
An ice cube is being heated steadily. The temperature reads 0 °C and stays there for two minutes before rising again. What is happening?
- AThe heating has been switched off
- BThe ice is melting — energy is going into the change of state
- CThe thermometer is broken
- DThe water is boiling
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Test yourself
6 questions · click to reveal each answer
What is a heating curve?
A graph of temperature against time as a substance is heated steadily.What is a plateau on a heating curve?
A flat part of the graph where the temperature stays the same even though heating is still going on.Why does the temperature stay flat while a substance is melting?
Because the energy being put in is used to break the particles free from their fixed positions (change the state), not to make them move faster. The thermometer only measures particle speed, so it doesn't change.How many plateaus does a normal heating curve have, and what is happening at each?
Two: one at the melting point (solid → liquid) and one at the boiling point (liquid → gas).What does temperature tell us about the particles?
How fast the particles are moving — that is, how much kinetic energy they have.For pure water, what temperatures would the two plateaus be at?
The melting plateau is at 0 °C and the boiling plateau is at 100 °C.
Exothermic reactions
By the end of this topic you'll know what an exothermic reaction is, why the surroundings get warmer, and be able to name some everyday examples.
Part 1Reactions that give out heat
Some chemical reactions give out energy. The energy is transferred from the reaction to the surroundings — that means everything around the reaction: the test tube, the water it's in, the air, your hand. Because energy is being given to them, the temperature of the surroundings rises.
A reaction that transfers energy to the surroundings is called exothermic. An easy way to remember it: exo sounds like "exit", and the energy exits the reaction. We can measure that an exothermic reaction has happened with a simple thermometer — the temperature goes up.
Keywords for Part 1
- Exothermic
- A reaction that transfers energy to the surroundings, so the temperature of the surroundings rises.
- Surroundings
- Everything around the reaction — the solution, the container, the air, your hand.
Part 2Everyday examples
Exothermic reactions are all around you. The big ones to remember:
Combustion (burning). Burning a fuel like methane, wood or a candle gives out a lot of heat and light. This is why a fire warms a room.
Neutralisation. When an acid reacts with an alkali, the mixture gets warmer — you can feel it on the side of the beaker.
Oxidation. When a substance reacts with oxygen (like iron slowly rusting, or hand-warmer iron filings reacting fast), energy is released.
Respiration. The reaction in your cells that releases energy from glucose is exothermic — it's part of why your body stays warm.
Keywords for Part 2
- Combustion
- Burning — a fuel reacting with oxygen, giving out heat and light.
- Neutralisation
- An acid reacting with an alkali (or base) to make a salt and water. It is exothermic.
- Respiration
- The reaction in living cells that releases energy from glucose. It is exothermic.
⚠ Watch out — exothermic doesn't just mean "explosions"
Lots of pupils think exothermic only means dramatic, violent reactions like explosions or roaring fires. It doesn't. Any reaction that releases heat is exothermic — including a gentle hand-warm neutralisation where the beaker just feels a few degrees warmer. The test is simple: does the temperature of the surroundings go up? If yes, it's exothermic, however small the change.
A student mixes an acid and an alkali in a beaker and notices the beaker feels warm. What kind of reaction is this?
- AEndothermic — it took heat in from the surroundings
- BExothermic — it gave heat out to the surroundings
- CNeither — neutralisation has no energy change
- DYou can't tell without weighing the chemicals
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6 questions · click to reveal each answer
What is an exothermic reaction?
A reaction that transfers energy to the surroundings, so the temperature of the surroundings rises.In an exothermic reaction, does the temperature of the surroundings go up or down?
Up — the surroundings get warmer because energy is given out to them.Name two examples of exothermic reactions.
Any two from: combustion (burning), neutralisation, oxidation, respiration.What piece of equipment would you use to show a reaction is exothermic?
A thermometer — you'd see the temperature rise."Exothermic reactions are always explosions." Is this true?
No. Any reaction that releases heat is exothermic, including gentle ones like a hand-warm neutralisation. It doesn't have to be violent.Why does a fire warm up a room?
Burning fuel is a combustion reaction, which is exothermic. It transfers energy to the surroundings (the air and objects in the room), warming them.
Endothermic reactions
By the end of this topic you'll know what an endothermic reaction is, why the surroundings get colder, and why an endothermic reaction feels cold — not hot.
Part 1Reactions that take heat in
Some reactions do the opposite of exothermic ones: they take in energy from the surroundings. Because energy is being pulled out of the surroundings, the temperature of the surroundings falls — things around the reaction get colder.
A reaction that takes in energy from the surroundings is called endothermic. The clue is in the name: endo means "into", and the energy goes into the reaction. Measure it with a thermometer and you'll see the temperature go down.
Keywords for Part 1
- Endothermic
- A reaction that takes in energy from the surroundings, so the temperature of the surroundings falls.
- Thermal decomposition
- Breaking a compound down using heat. You have to keep supplying energy, so it is endothermic.
Part 2Everyday examples
Endothermic changes are less obvious than exothermic ones, but here are the ones to know:
Thermal decomposition. Heating a compound to break it apart — like heating copper carbonate or calcium carbonate. It only keeps going while you keep heating it.
Citric acid + sodium bicarbonate. This is the fizzy reaction in sherbet. Mix the two and the temperature drops — that's why sherbet can feel cool on your tongue.
Some dissolving. Dissolving certain salts (like ammonium nitrate) in water takes in energy and makes the water colder.
This is exactly how an instant cold pack works. Snap it and a salt mixes with water; the endothermic process pulls heat in, so the pack turns cold and you can use it on a sports injury.
⚠ Watch out — endothermic reactions feel COLD, not hot
The word "thermic" makes people think endothermic means "hot". It's the opposite. An endothermic reaction takes heat in — including heat from your hand and the surroundings — so it feels cold. If you hold a beaker where an endothermic reaction is happening, your hand is one of the "surroundings" giving up its heat, which is why your hand feels cold. Heat in = feels cold.
A student dissolves a salt in water and the thermometer reading drops from 21 °C to 14 °C. What kind of change is this?
- AExothermic — the temperature changed
- BEndothermic — the temperature fell, so heat was taken in
- CExothermic — dissolving always gives out heat
- DNeither — dissolving is not a chemical change so it has no energy change
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What is an endothermic reaction?
A reaction that takes in energy from the surroundings, so the temperature of the surroundings falls.In an endothermic reaction, does the temperature of the surroundings go up or down?
Down — the surroundings get colder because energy is taken from them.Name two examples of endothermic changes.
Any two from: thermal decomposition, citric acid + sodium bicarbonate (sherbet), some dissolving (e.g. ammonium nitrate).Does an endothermic reaction feel hot or cold? Explain.
It feels cold, because it takes heat in from the surroundings — including from your hand. Your hand gives up its heat to the reaction, so it feels cold.How does an instant cold pack work?
Snapping it lets a salt mix with water. This is an endothermic process that takes heat in, so the pack turns cold.Why is thermal decomposition endothermic?
You have to keep supplying energy (heating) to break the compound apart. The reaction takes that energy in, so it is endothermic.
Investigating energy changes
By the end of this topic you'll be able to plan a fair test, work out a temperature change, and use the sign of that change to say whether a reaction is exothermic or endothermic.
Part 1The practical: before and after
To find out whether a reaction gives out heat or takes it in, you do something beautifully simple: measure the temperature before and after the reaction.
Measure the starting temperature of the chemicals with a thermometer. Mix them, stir, and read the highest (or lowest) temperature you reach. Then work out the temperature change:
temperature change = final temperature − start temperature
The sign of the answer tells you everything:
· A rise (the change is positive, the temperature went up) means the reaction is exothermic — it gave out heat.
· A fall (the change is negative, the temperature went down) means the reaction is endothermic — it took heat in.
Keywords for Part 1
- Temperature change
- Final temperature minus start temperature. A rise means exothermic; a fall means endothermic.
- Fair test
- A test where you change one thing and keep everything else the same, so the comparison is valid.
Part 2Making it a fair test
To compare reactions fairly, you need to think about your variables:
The variable you change (independent variable) — for example, which acid you use, or its concentration.
The variable you measure (dependent variable) — the temperature change.
The variables you keep the same (control variables) — the volume of liquid, the starting temperature, the same thermometer, the same type of cup or beaker. Keeping these the same is what makes it a fair test.
It helps to write your readings in a results table so you can compare them at a glance:
Worked example — finding a temperature change
A student mixes an acid and an alkali. The temperature at the start is 20 °C. After mixing, the highest reading is 27 °C. Calculate the temperature change and state whether the reaction is exothermic or endothermic.
Worked example — a temperature that falls
A student dissolves a salt in water. The start temperature is 22 °C and the lowest reading is 15 °C. Calculate the temperature change and state the type of reaction.
⚠ Watch out — get the direction of energy flow the right way round
It's easy to muddle up which way the energy is going. Hold on to this: a temperature rise means the surroundings gained energy, so the reaction gave heat out → exothermic. A temperature fall means the surroundings lost energy, so the reaction took heat in → endothermic. Warm = heat out; cold = heat in.
A reaction starts at 19 °C and ends at 9 °C. What is the temperature change, and what type of reaction is it?
- A+10 °C, exothermic
- B−10 °C, endothermic
- C−10 °C, exothermic
- D+28 °C, exothermic (added the readings)
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How do you investigate whether a reaction is exothermic or endothermic?
Measure the temperature before and after the reaction with a thermometer, then work out the temperature change.Write the equation for temperature change.
temperature change = final temperature − start temperature.A temperature rise tells you the reaction is which type?
Exothermic — heat was given out to the surroundings.A reaction starts at 18 °C and finishes at 25 °C. Calculate the change and state the type.
change = 25 − 18 = +7 °C (a rise) → exothermic.A reaction starts at 23 °C and finishes at 16 °C. Calculate the change and state the type.
change = 16 − 23 = −7 °C (a fall) → endothermic.Name two control variables you would keep the same in this practical.
Any two from: volume of liquid, starting temperature, same thermometer, same type of cup/beaker. Keeping these the same makes it a fair test.In a fair test, what is the dependent variable here, and what is one possible independent variable?
The dependent variable (what you measure) is the temperature change. An independent variable (what you change) could be the concentration of the acid (or which acid you use).